I'm running on linux with mysql but I suspect it's not too different from what you have. On mine there is a table in the database called ofUser that lists your users. If you're using LDAP integration then there will likely not be very many records in that table. There is also a record in the table 'ofProperty' that holds a list of administrators. The record you want has 'admin.authorizedJIDs' in the name field. The value field contains a comma separated list of admins. On my system this is the email address of each admin user.
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Locked myself out of Openfire console
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